Slovenian Researchers Turn Biomass Waste into High-Performance Aggregates

In a significant stride towards sustainable construction, researchers have unveiled a novel method to transform biomass fly ash (BFA) into lightweight, high-performance aggregates. This innovation, detailed in a recent study published in *Case Studies in Construction Materials* (translated as *Case Studies in Building Materials*), not only addresses the growing demand for natural aggregates but also offers a viable solution for large-scale waste utilization and carbon sequestration.

At the heart of this research is Anže Tesovnik, a scientist from the Slovenian National Building and Civil Engineering Institute and Jožef Stefan International Postgraduate School. Tesovnik and his team have pioneered a technique that uses alkali-activated materials (AAMs) derived solely from BFA to produce artificial lightweight aggregates. The process involves a variable rotation speed approach and systematic variation of alkali content and solution density, all while maintaining a constant water-to-solids ratio.

The study’s findings underscore the critical role of alkali concentration in granulation, revealing that it significantly influences the process beyond what can be attributed to water availability alone. “Alkali concentration is a key factor in the granulation process,” Tesovnik explains. “It’s not just about the water; the alkali content plays a pivotal role in determining the final properties of the aggregates.”

The researchers also investigated the interplay between alkali activation and carbonation, exploring different mix designs and curing conditions. They compared simultaneous curing carbonation with post-cure carbonation, evaluating the effects on both macro- and microstructural properties and leaching behavior.

The results were striking. Prolonged carbonation initiated after aggregate formation led to premature depletion of calcium, limiting the development of C-A-S-H gels and increasing microporosity. This, in turn, reduced mechanical properties. However, post-curing carbonation maintained a compressive strength of over 1 MPa while still allowing the benefits of carbonation, resulting in compressive strengths comparable to lightweight expanded clay aggregates.

Carbonation also proved to be an effective leaching mitigation strategy. It stabilized heavy metals through both physical encapsulation and chemical pH regulation, addressing a significant environmental concern.

The implications of this research are far-reaching. For the energy sector, this innovation offers a sustainable pathway for BFA valorization, a critical consideration given the regulatory restrictions on its direct use in cement. It also contributes to carbon capture and circular economy initiatives, aligning with global efforts to reduce carbon emissions and promote sustainable practices.

As the construction industry grapples with the challenges of waste management and environmental sustainability, this research provides a promising avenue for innovation. By transforming waste into valuable construction materials, it paves the way for a more sustainable future.

Tesovnik’s work highlights the importance of carbonation timing in high Ca AAMs and underscores the potential of lightweight aggregates as a viable solution for BFA valorization. As the industry continues to evolve, such innovations will be crucial in shaping a more sustainable and circular construction sector.

In the quest for sustainable construction materials, this research marks a significant milestone. It not only offers a solution to the growing demand for natural aggregates but also provides a viable pathway for waste utilization and carbon sequestration. As the industry continues to evolve, such innovations will be instrumental in shaping a more sustainable and circular construction sector.

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