In the quest for more sustainable and efficient refrigerants, a recent study published in *Zhileng xuebao* (translated as “Refrigeration Journal”) has shed light on promising alternatives for automotive heat-pump air conditioners. Led by Sun Sainan, the research delves into the performance of low-GWP (Global Warming Potential) mixed refrigerants, offering insights that could reshape the energy sector’s approach to cooling technologies.
The study compares the thermophysical properties and cycle performances of various refrigerant mixtures, including R134a, R1234yf, R290, R410A, and eight mixtures containing the flame retardant R1216. Among these, the binary mixture R152a/R1216 (60/40) stands out, exhibiting similar properties to the widely used R134a but with an approximately 11% increase in the heating coefficient of performance (COP). This enhancement could translate to significant energy savings in real-world applications.
“Our findings indicate that these mixtures are not only environmentally friendly but also stable in operation,” Sun Sainan noted. “The potential for improved efficiency and lower GWP values makes them highly attractive for future applications.”
The research also highlights the superior volumetric cooling and heating capacities of certain mixtures, such as R290/R1216 (60/40) and R1234yf/R161/R1216 (40/40/20), which range from 113% to 180% that of R134a. These mixtures could be particularly beneficial in small mobile cooling systems, such as electric-vehicle heat pumps, where space and efficiency are critical.
However, the study also notes that while these mixtures show great promise, further experimental validation is necessary before they can be widely adopted. “The theoretical performance is promising, but real-world testing is essential to confirm these results and ensure safety and reliability,” Sun Sainan added.
The implications for the energy sector are significant. As the demand for more sustainable and efficient cooling solutions grows, these low-GWP mixed refrigerants could play a crucial role in reducing the environmental impact of automotive air conditioning systems. The research published in *Zhileng xuebao* provides a solid foundation for future developments, paving the way for innovations that could transform the industry.
As the world moves towards greener technologies, the insights from this study could guide manufacturers and policymakers in making informed decisions that balance environmental concerns with performance and commercial viability. The journey towards sustainable cooling is complex, but with research like this, the path forward becomes clearer.

